Fluorescence line narrowed spectra of Zn and metal-free cytochrome c

Fluorescence line narrowing (FLN) spectroscopy was used to study the role of the polypeptide chain in influencing the spectrum of Zn-substituted cytochrome c (Zn cyt c) and metal-free cyt c (porphyrin cyt c). For both derivatives the spectra show characteristics of relaxed fluorescence from an inhomogeneously broadened sample. Zero phonon lines and phonon wings can be clearly distinguished, and vibrational frequencies of the ground and excited states were identified. The inhomogeneous distribution width for porphyrin cyt c is slightly wider than that of Zn cyt c and a second population of molecules was apparent in the porphyrin cyt c. The phonon coupling was greater for Zn cyt c than for porphyrin cyt c, which may be due to the extra coupling to the polypeptide chain by metal ligation.This work has been done in partial fulfillment of the requirements for the Doctor of Philosophy degree.     

On operators and search space topology in multi-objective flow shop scheduling

Multi-objective optimization using evolutionary algorithms identifies Pareto-optimal alternatives or their close approximation by means of a sequence of successive local improvement moves. While several successful applications to combinatorial optimization problems are known, studies of underlying problem structures are still scarce.     

激光标线的原理和实验

根据几何光学知识分析了激光标线原理.理论和实验表明:激光标线长度与激光光束形状、光学元件形状及材料折射率有关.并讨论了激光标线向两侧扩展的原因.     

R~(2,1)中线性Weingarten曲面的Bcklund变换(英文)

本文对三维Minkowski空间R~(2,1)中具有性质K-2mH+m~2-l~2=0或H=constant的类时曲面定义了一个Darboux线汇,同时得到了相应的Bcklund变换。     

Strong asymptotics in Lagrange interpolation with equidistant nodes

In this paper we prove three conjectures of Revers on Lagrange interpolation for f_λ(t)=|t|^λ,λ>0, at equidistant nodes. In particular, we describe the rate of divergence of the Lagrange interpolants L_N( f_λ,t) for 0<|t|<1, and discuss their convergence at t=0. We also establish an asymptotic relation for max_|t|1| |t|^λ−L_N( f_λ,t)|. The proofs are based on strong asymptotics for |t|^λ−L_N( f_λ,t), 0|t|<1.     

非线性最小二乘问题的信赖域方法

本文提出一个新的非线性最小二乘的信赖域方法,在该方法中每个信赖域子问题只需要一次求解,而且每次迭代的一维搜索步长因子是给定的,避开一维搜索的环节,大大地提高了算法效率.文中证明了在一定的条件下算法的全局收敛性.     

Numerical analysis for stochastic age-dependent population equations with Poisson jumps

In this paper, stochastic age-dependent population equations with Poisson jumps are considered. In general, most of stochastic age-dependent population equations with jumps do not have explicit solutions, thus numerical approximation schemes are invaluable tools for exploring their properties. The main purpose of this paper is to develop a numerical Euler scheme and show the convergence of the numerical approximation solution to the true solution.     

CCD光谱谱线标定方法研究

CCD作为光谱分析和测色仪器的光谱接收器件 ,光谱谱线定位受单色仪狭缝和CCD光敏元尺寸影响。提出采用最小二乘法做曲线拟合和质心法来确定光谱线在CCD上的精确定位 ,使光谱谱线的定位精度得到提高 ,并且不受CCD光敏元尺寸限制。实验结果表明 ,两种方法对光谱线的定位 ,具有重复性高 ,稳定性好等特点。在定位精度上 ,两者具有一致性。     

拓扑系统的紧性和分离性

考察拓扑系统的两种紧性——空间式紧和locale式紧,给出紧性的若干刻画,讨论了两种紧性的相互关系,证明了拓扑系统的两种紧性都是拓扑空间紧性的良好推广,说明了紧拓扑系统的闭子拓扑系统、有限和系统以及积系统仍是紧拓扑系统。最后在拓扑系统中考察了紧性加强分离性的问题,得到了紧,(强)T2拓扑系统为(强)T3,(强)T4拓扑系统等结论,并用理想收敛刻画了拓扑系统的强T2分离性。